Written and Psychological Contracts of Employment

The basic nature of employee-employer interaction is dictated by the nature of exchange in the employment relationship. An employment relationship is a contract based on a mutually agreed on, voluntary made exchange of promises. In this exchange, each party stands to gain if the exchange agreement is fulfilled and again, each party loses if it is not (Spielberger, 2008, p. 494)Advertising We will write a custom essay sample on Written and Psychological Contracts of Employment specifically for you for only $16.05 $11/page Learn More A contract is always born from between the employer and employee when the employee agrees the terms of employment in which case the acceptance may entail paperwork or just a word of mouth. There are three elements to the contract: offer, an â€Å"acceptance,† and consideration, which typically takes the form of a â€Å"promise by the employee to perform services in exchange for the promise by the employer to pay for su ch services† (Reid and Standryk, 2004) The employment relationship is usually documented in a contract of employment which can be a written statement contains certain terms and conditions regarding a given job. However, it necessarily does not have to be in writing, in which case it is called a psychological contract. The basic indication of the existence of an employment contract is the consent of both the employee and the employer to fulfill their obligations, with the former willing to work with expectation of compensation from the latter. It is from this contract that the basis for the relationship between the two parties is drawn, with the contract giving both parties certain rights and obligations called contractual terms, which should complement the rights enjoyed under the statutory labor laws, for example, the right to paid annual leave. Here, an introduction into the content and nature of the employment relationship is given, followed by a definition of the written c ontract of employment, expounding on the statutory rights, formation, and termination. In addition, the psychological contract of employment is discussed which includes its formation and breach. Key Differences between Written and Psychological Contracts of Employment The main difference between a written and psychological contract lies on how they are made such that, a written contract is always documented and provides duties and responsibilities in a generalized form, while psychological contract involves perceive obligation on the part of both employer and employee. In this case, a written contract will require have specific wording regarding the responsibilities of either party as well as terms of the contract while a psychological contract will only entail reasonable judgement about responsibilities one should undertake.Advertising Looking for essay on business economics? Let's see if we can help you! Get your first paper with 15% OFF Learn More According to Robi nson (1996), Psychological contracts tend to be primarily subjective as they depend on what either party to the contract believes is contained in the promise, in which case both parties may have contradicting interpretation. On the other hand, written contracts are objective and clearly stated in the contract form such that both parties expect the same results from the contract. Due to the uncertainty nature of the psychological contracts, it is always difficult to resolve disputes, more so because evidence of agreement may not be categorically substantiated unlike in written contracts where signed and formalized documentation cannot be ignored. Psychological contracts are normally established informally through dialogue between the employer and employee on the role each of them can perform in the contract, without specifically outlining the details of the duties each party will perform. In the case of written contracts, the contract document will contain explicit outline of duties and expectations of the contract, which must be signed by the both parties, thus acting as compete piece of evidence in the event a dispute arises. Although it is important to provide all employees with written contracts, some assignments such as freelancer may not need written contracts. Breach of the psychological contract basically arises when either party to the contract feels that the other party has not fulfilled his obligation as promised. Since the magnitude of the breach may not be explicitly defined, the person who feels aggrieved will be affected psychologically and emotionally, with the response being loss of loyalty or loss of motivation, thus leading to general underperformance in the long run. Worse still, unresolved breach of psychological contracts may prove costly especially if there interference with the firm’s reputation as perceived by outsiders (Robinson, 1996). On the other hand, breach of written contracts is easily quantified, especially where either party fails to meet expectations, while resolution for the same is always included in the contract form. Formation of a written employment contract normally takes place upon the commencement of the contractual obligation, and according to the statutory requirement, the employer has the mandate to ensure the written contract form is provided to the employee not more than two months after the first day of employment. Therefore, any instance of holding the contract document, as is the case with some employers, is a violation of law, while the employee has the right to demand for the same without any form of intimidation.Advertising We will write a custom essay sample on Written and Psychological Contracts of Employment specifically for you for only $16.05 $11/page Learn More Under the written contracts, terms and conditions of termination are explicitly stated, which in most cases may include lapse of time, mutual agreement, one party giving notice of term ination or summary dismissal especially due to breach of terms. However, there are instances where legal redress may be sought especially when there is no ‘just cause’ for termination. Using Appropriate Theoretical Discussion, Identify How Psychological Contracts Can Be Broken By Employers Employees’ perceptions of employer psychological contract fulfillment/breach provide the basis upon which employees reciprocate. The assumption made here is that employees have delivered on the terms of their exchange so that the basis for employer reciprocation (i.e. employer fulfillment of obligations) exists (Conway and Coyle-Shapiro, 2006). One challenge arises on how to measure that the psychological contract has been breached, given that what one perceives as a breach may not necessarily appear as breach of contract to the other. For instance, some changes in the behavior of the boss concerning the relationship with employees such as refraining from routine morning greeti ngs or reverting to phone conversations instead of routine face to face discussions may appear as a breaking the psychological contract to the employee, but not to the employer. However, certain breaches of contract have far-reaching effect, thus should be addressed before they become detrimental to the firm. Poor human resource policies are likely to cause breach of psychological contracts from the employee’s perspective. In some cases, employees will perceive a broken psychological contract when promises made by the employer about human resource practices do not add up to what is actually delivered (Conway and Briner, 2005, p. 65). Employees require mentorship, guidance, and support from their boss while in the organization. Where such support is unavailable, employees feel that their social well-being is ignored and that the employer has failed to perform his part of psychological contract (Conway and Briner, 2005, p. 65). The ever-changing business environment including c ompetition in the labour market has forced organization to rethink their strategies, more so in human resources, with the primary aim being to improve employment relationship.Advertising Looking for essay on business economics? Let's see if we can help you! Get your first paper with 15% OFF Learn More As a result of the dynamic climate, employment contractual relationships are becoming more and more threatened, while the hitherto security of tenure and reward for employee loyalty and performance is changing shape. Indeed, psychological contracts are becoming even more risky as most employers and employees alike are more likely to breach their part of bargain (Robinson, 1996). Oftentimes, employees will perceive that employers have broken their contractual obligation and will always react through reducing their level of performance, changing the way they behave in the organization, and always seeking an opportunity to leave the firm for another. Conclusion The world of business is rapidly changing, especially with globalization bringing about integration of both commodity and labour markets on a global level. In this case, competition has gone a notch higher, calling for organizations to restructure their internal resource policies, more importantly on human resources in order to attain a competitive advantage; indeed, organizations are â€Å"pressured to make rapid changes and accommodations to their workforce and employment policies† (Cappelli, 1999, Coffey, Cook, and Hunsaker, 1994). Moreover, it is becoming important for employers to appreciate the role played by employees in organizations’ performance and must find a balancing act on how they must â€Å"manage, renegotiate, and in some cases, violate the psychological contract that they have established with their employees† (Rousseau 1995). Nevertheless, it is paramount that organizations rethink on the effective way to fulfill their roles in psychological contracts in addition to formal written contract given that such contracts are almost inevitable, otherwise they will be always under financial and reputation risk. Reference List Cappelli, P., 1999. The new deal at work: managing the market-driven workforce. MA, Harvard Business Press. Coffey, R. E., Cook C. W., and Hunsaker, P. L., 1994. Management and Organizational Behavior. 3rd Edition. NY, McGraw-Hill/Irwin. Conway, N. and Briner, R. B., 2005. Understanding psychological contracts at work: a critical evaluation of theory and research. NY, Oxford University Press. Conway, N. and Coyle-Shapiro, J. A. M., 2006. Reciprocity and Psychological Contracts: Employee Performance and Contract Fulfillment. London, WC1E 7HX, UK. Web. Reid, R. B. and Standryk, L. E., 2004. The Written Employment Contract. Lancaster. Brooks Welch LLP. Web. Robinson, L. S., 1996. Trust and Breach of the Psychological Contract. Journal of Administrative Science Quarterly, Vol. 41. Web. Rousseau, D. M., 1995. Psychological contracts in organizations: understanding written and unwritten agreements. NJ, SAGE. Spielberger, C. D., 2008. Encyclopedia of Applied Psychology. Volume 2. MO, Academic Press. Web. This essay on Written and Psychological Contracts of Employment was written and submitted by user Arjun P. to help you with your own studies. You are free to use it for research and reference purposes in order to write your own paper; however, you must cite it accordingly. You can donate your paper here.

Indonesian Nationalism essays

Indonesian Nationalism essays Nationalism as the dominant force behind the Indonesian independence movement is the leading theme presented in the video, Barrel of a gun. The turn of the twentieth century marked the beginning of nationalist stirrings in Indonesia against the ruling Dutch empire. Fuelled by dissent and second-class treatment, nationalistic ideals and propaganda began to spread throughout the native Indonesian population and ignite. However, the spread of nationalism would not have been so great without particular factors. Firstly, Sukarno, as the charismatic leader of the movement laid the foundations of a nationalist stronghold. Secondly, the Japanese invasion during World War 2 paved a pathway for Indonesian independence. Thirdly, international support for the Indonesian push against a dominant western power, finally tipped the rule of the Dutch colonialists. Nationalism in Indonesia culminated with independence being achieved in 1949. (Osborne, 1997; 154-161) ( Barrel of a Gun, Video) The emergence of a pro-independence nationalistic movement stems from Dutch educated Indonesians in the early part of the twentieth century. The Russo-Japanese war of 1905 demonstrated for the first time, the ability for an Asian nation to defeat a major Western power. ( Heidhues, 2000; 122) This ignited fervent belief amongst Indonesian intellects to overcome the conquering Dutch. However, early attempts in the 1920s at revolution backfired. Without the mass support of the Indonesian population, the early uprisings headed by the Indonesian Communist Party, were quelled, resulting in many Indonesians becoming prisoners and being exiled. ( Church, 1995; 45) It was during this period that the most influential and charismatic of leaders surfaced, Sukarno. Unlike the Vietnamese spread of nationalism whereby there was only one party striving for independence, Sukarno and his Communist party were the leading party out of numerous nationalis...

Science policy studies - Was there a BSE crisis Essay

Science policy studies - Was there a BSE crisis - Essay Example This disease is characterized by a 4 – 5 years incubation period and its effects are adverse; after a few weeks of its onset, it often leads to the death of cattle. Researchers have indicated that as BSE gets into the brain of cattle; the spinal cord and the brain itself get affected, resulting to lesions that have alterations that are sponge-like. These lesions can be seen under the normal microscope. Some researchers have also indicated that the BSE agent is very stable, with the capability of resisting heat, drying and freezing, and more critically, resisting heat applicable in the processes of sterilization and pasteurization. This property has raised a controversy over BSE agent’s nature, as several theories have sought to explain such nature. It has been generally assumed that the BSE was derived from the disease scrapie, which occurs in sheep (Millstone and van Zwanenberg, 32), though there is no any evidence from experiments to show that this assumption is true. Further, there lacks a proof to show that BSE agent would behave like scrapie agent, which does not find its way into the human beings, when they consume the meat products that are from infected animals. Generally, the roots of the BSE crisis dates back to the traditional food policy-making and UK Agriculture. The scientists in the UK first unravelled the disease in 1986 and by the year 2002, cases preceding 181, 376 had been confirmed. After the initial discovery, the disease had also been confirmed out of the UK from 1989. This led to an alarming call that initiated the introduction of programmes for monitoring the spread of the BSE in cattle that were slaughtered or found dead. 12 countries unveiled the presence of the disease in their territories including Spain, Slovenia, Slovakia, Poland, Japan, Italy, Israel, Greece, Germany, Finland, Czech Republic and Austria (Bovine spongiform encephalopathy, 4). Measures for preventing

Strategic Planning for Tourism in Abu Dhabi Essay

Strategic Planning for Tourism in Abu Dhabi - Essay Example However, the primary aim of this paper is to identify role of Masdar in improving the travel and tourism industry Masdar City and to develop a set of plausible and actionable strategic recommendations to the company that will help it in this respect. Currently, the company has five units i.e. Masdar City, Masdar Power, Masdar Carbon, Masdar Capital and Masdar Institute (Masdar-b, n.d). This paper will attempt to deal with the company’s Masdar City as this unit is engaged in infrastructural development that lead to the growth of the travel and tourism industry. This unit strives to develop a â€Å"global clean-technology cluster† called Masdar City which is situated â€Å"17km from downtown Abu Dhabi† (Masdar-c, n.d.). Masdar City can be developed as a major tourists’ destination. The company is aiming to develop this city backed with renewable energy and it is well designed with 40,000 residents. The primary essence of the Masdar City is on innovative tech nologies through R&D. United Arab Emirates (UAE) is now focusing on its tours and travel industry. The UAE Government has aimed to develop its important cities as a popular tourist attraction. For example, in Dubai, the leisure and hotel industry has grown significantly. The travel and tourism industry of Masdar City has a direct competition with Dubai. Moreover, other Gulf countries like Saudi Arab, Kuwait, and Oman etc are also trying to develop their travel and tourism industry. On the other hand, Middle East courtiers like Egypt are major tourist destinations and they are the major competitor of Masdar City in travel and tourism industry (Deulgaonkar, 2011). Tourism and travel industry primarily belong to global market as it targets entire global population. Therefore, the competition in travel and tourism industry is very high. 1.2. Communications Analysis The Masdar is highly respectable company of UAE and it has developed a higher corporate image in the market. The company is a focus-point for the entire nation as it is one the most developed renewable energy company. It has been continuously working for the development of the entire country especially for Abu Dhabi. One of the major tools for the company is its communicational and promotional activities. Its corporate website is critical medium for developing communication with its target audience. In order to develop ‘two-way’ communicational system, it has partnered with several social networking sites like Facebook, Twitter etc. It is also using its website for its advertising strategies and for delivering market signals. The organization generally communicates with target audience to spreading awareness regarding renewable energy, its projects, recent developments etc. Its communicational developments can play a very significantly role in developing the Masdar City as major tourists’ attraction. 1.3. Issue Analysis The Masdar has been successfully maintaining its public relation with its target audience through media partnering and through its corporate website. However, in order to develop the tourism industry of Masdar City in the global market, its communication is not unique and effective. It must be taken into consideration, that for competing in the global market, its communication must reach to global market.

Uk and Eu have created a legal and regulatory system that encourages Essay

Uk and Eu have created a legal and regulatory system that encourages the adoption and growth of e-commerce - Essay Example 41). This piece of research paper addresses the regulatory activities of UK and EU in last 15 years to encourage the adoption and growth of E-Commerce and how it has provided a framework to protect the rights of consumers. An Overview of EU’s E-Commerce Directive In 2000, European Union has first adopted regulations to foster E-commerce throughout the regions of EU (Plotkin, Wells and Wimmer, 2003, p. 14-60) and in 2002 it also has set certain rules and regulations in order to provide consumers within the EU with more comforts in buying of goods or services from online. One of the very fundamental objective of this regulation was to ensure that customers’ rights are protected. These rules and regulations have clearly defined how the protection can be applied. The protection applied only to those consumers who visited a commercial website setting specific directions regarding how a business should operate its website and virtual business environment (Sparrow 2009, p. 41) . According to EU regulations, every company that operates a virtual website must adhere strictly to the rules and regulations if the business offers good or services to its customers online. When a business fails to strictly comply with these regulations, the business will be legally liable and will be prosecuted accordingly. EU’s regulations about E-Commerce has been considered to be a cornerstone in electronic marketplace. These regulations, often termed as E-Commerce Directive or Distance Selling Directive, were established in 2000 to foster the expansion of E-Commerce by developing a ‘country of origin’ rule that promoted free movement of E-Commerce within the EU member countries. The regulations have defined the limit of how extent one member state may regulate electronic commercial activity entering its boarders from another member state (Plotkin, Wells and Wimmer, 2003, p. 14-60). Sparrow (2009, p. 41) stressed that the E-Commerce directive developed by E U was to encourage greater use of E-Commerce by removing the barriers throughout the Europe and to enhance consumers’ confidence by making them and businesses aware of their rights and obligations to each others when dealing through online. The regulations were more likely to promote a single market in Europe by developing movement of ‘information society services’ across the European economic area. EU directive as British Law Internet Magazine in 2002 reported that the E-Commerce regulations implemented by EU has also been adopted by UK and considered as its Law. When it has been considered as part of English law, the wide-ranging legislation particularly affected ISPs and how the businesses would be held if they dealt with illegal content on the websites. When UK has adopted the EU directive, the major intentions were to boost confidence in e-commerce. According to UK’s regulations, those businesses that failed to adhere to the regulations have been subj ect to a ‘stop now’ order by which these businesses were forced to change their online-procedures or business practices. EU Directive promoted growth of E-Commerce Computer Weekly in 2003 reported that European Union’s E-Commerce Directive has already increased the take-up of online services and proved highly

Unexpected Halide Transfer: Aluminium and the Lanthanoids

Unexpected Halide Transfer: Aluminium and the Lanthanoids Unexpected Halide Transfer: Complex Reorganisation Between Aluminium and the Lanthanoids. Glen B. Deacon, David J. Evans and Peter C. Junk.* This submission was created using the RSC Communication Template (DO NOT DELETE THIS TEXT) (LINE INCLUDED FOR SPACING ONLY DO NOT DELETE THIS TEXT) [Pr(MeCN)9][AlCl4]3.MeCN undergoes reorganisation upon the addition of an ether. In the case of recrystallisation from tetrahydrofuran, the ionic nature is lost, whereas the addition of crown ether gives reorganisation, whilst maintaining ionic character. Isolation of homoleptic ionic trivalent lanthanoid complexes, under non aqueous conditions, has been investigated using nitrogen based ligand systems 1-5. The interest surrounding these homoleptic complexes is attributed to their potential catalytic properties 3,5. Under non aqueous conditions, the use of highly labile ligands, such as solvent molecules, presents the possibility of exposing the metal centre, hence providing a site for catalysis and thus can be considered to be ‘near naked 3. Complexes involving Ln3+ ions, that can be considered ‘near naked’ have to date been restricted to complexes such as [Ln(MeCN)n]3+ , with anions such as AsF6 and AlCl4 3-5. With this in mind, we have investigated the ability to access homoleptic ‘near naked’ Ln3+ complexes with tetrahydrofuran (thf) ligands. Currently, no such complexes have been reported for the smaller trivalent species unlike the larger divalent species, for which there is precedent viz. [Sm(thf)7][BPh4]2 6. Exploitation of the coordination abilities of crown ether has been investigated with the isolation of [ScCl2(18-crown-6)][FeCl4]. Via Sc n.m.r it has been shown that [ScCl(thf)(18-crown-6)][FeCl4]2 and then subsequently [Sc(thf)2(18-crown-6)][FeCl4]3 can be synthesised even though it has not been structurally characterised. With this in mind it should therefore be possible to isolate similar adducts in MeCN. Results and Discussion Homoleptic acetonitrile Ln3+ complexes can be obtained via two pathways viz equations 1 and 2 3. It was our intention to extend this chemistry to involve homoleptic Ln3+ complexes with ether ligands in place of MeCN. In reactions analogous to equations 1 and 2 with thf in place of MeCN, we found to our surprise [LnCl3(thf)2]n (Ln = Pr, Nd) was the sole Ln complex isolatable. This suggests that the complex is formed by a concerted process whereby AlCl4 binds to Ln3+ releasing AlCl3, allowing binding of another AlCl4 and so on until complete halide transfer to Ln3+ occurs yielding LnCl3(thf)n (equations 3, 4). Similarly, addition of 18-crown-6 to [Pr(MeCN)9][AlCl4]3 resulted in reorganisation to [(PrCl(à ¯Ã‚ Ã‚ ­Ã¢â‚¬â€œCl)(18-crown-6))2][AlCl4]2.2(MeCN) (1) † . Isolation of 1 illustrates there is an equilibrium in solution involving [Pr(MeCN)9][AlCl4]3.(MeCN). Conductivity measurements show a 1:3 electrolyte 7.This is in contrast to that previously reported for the Sm complex by Hu and supported by Bà ¼nzli for which a 1:2 is electrolyte is reported 4,8. We believe that the complex [Ln(MeCN)9][AlCl4]3.(MeCN) undergoes rearrangement in solution ranging from a 1:3 down to a 1:2 electrolyte (equation 5). This change in coordination environment of the lanthanoid metal establishes the pathway to halide transfer involving a transient species related to that shown in Figure 1. Structural motifs similar to this have been observed for several lanthanoid complexes including [Sm(ÃŽÂ ®6-C6Me6)(AlCl4)3] .toluene 9,10. The reaction is completed by the substitution of MeCN by the crown ether and cleavage of the bridging Al–Cl bonds in a similar fashion to that observed for reactions involving thf. Complex 1 has a nine coordinate Pr centre that is bound to all six oxygens of the crown ether. The Pr is also bound to one terminal and a bridging chloride, and dimerises through an inversion centre. There is a distinct change in bond lengths between the terminal (Pr-Clter 2.715(2)Ã…) and bridging chlorides (Pr-Clbr 2.839(2) and 2.858(2)Ã…) as would be expected with similar changes identified in [PrCl(à ¯Ã‚ Ã‚ ­-Cl)(tetraethyleneglycol)]2 11. The distances for Pr-Ocrown range from 2.572(4) 2.590(7)Ã…, following the same trends in the related cation [(DyCl(à ¯Ã‚ Ã‚ ­Ã¢â‚¬â€œCl)(dibenzo18-crown-6))2][(DyCl3(à ¯Ã‚ Ã‚ ­Ã¢â‚¬â€œCl)(MeCN))2] 12, albeit with a lengthening of Ln-O in line with increased ionic radius between Dy and Pr. The crown ethers adopt a saddle type morphology with the metal residing in almost the centre of the cavity made by the O1, O3, O4, O6 (0.601Ã…) plane and the O2, O5 (0.491Ã…) plane. The crown ether collapses to accommodate the smaller size of the Pr3+ which is evident in the planes derived by the oxygen atoms of the crown. The angle between plane 1 (O1, O2, O5, O6) and plane 2 (O2, O3, O4, O5) is 125.71o showing this slight closure to ensure that the oxygen atoms are all bound. This closure of the crown ether is observed for all the Ln3+ 18-crown-6 complexes in which the angle closes from 129.74o in complex [LaCl3(18-crown-6)] 13 through to 68.95o in [Lu(CH2(SiCH3))2(18-crown-6)][(CH2(SiCH3))B(C6H5)3].C2H4Cl2 14 owing to the reduction in size of the ionic radius of the Ln centre. Notes and references All reactions were carried out under dry nitrogen using dry box and standard Schlenk techniques. Solvents were dried by distillation from sodium wire/benzophenone (thf) or CaH/P2O5 (MeCN). IR and far IR data were obtained as described previously 15. Metal analyses were carried out by complexiometric EDTA titration with the addition of 5% sulphosalicylic acid to mask Al 16. Anhydrous AlCl3, LnCl3, and 18-crown-6 were supplied by Sigma Aldrich. AlCl3 was freshly sublimed prior to use. Conductivity measurements were carried out on a Crison Conductimeter 522 (serial no; 3807), using a locally manufactured air-sensitive cell. The complex [Pr(MeCN)9] [AlCl4]3 was made using previous published methods 3 and conductivity measurements were carried out as mentioned above (367.97 S cm2 mol-1 1.097 x 10-3 mol dm-3, MeCN). 1: Method A: [Pr(MeCN)9][AlCl4]3. MeCN (0.20g, 0.19 mmol) and 18-crown-6 (0.20g, 0.57 mmol), was dissolved in MeCN (30 ml). The solution was stirred and heated to near boiling to assist dissolution. The resulting green solution was then filtered and reduced in-vacuo. The solution was then cooled at -30oC yielding small green crystals. (0.21 g (81%)). m.p. 170oC(dec), C28H54Al2Cl12N2O12Pr2; calcd. Pr 10.27; found Pr 10.68%. I.r absorption (Nujol): cm-1. Unit cell collection confirms the same product as via method A. Method B: A mixture of PrCl3 (0.10 g, 0.40 mmol), AlCl3 (0.16 g, 1.20 mmol) and 18-crown-6 (0.29g, 0.83 mmol), was dissolved in MeCN (30 ml). The solution was stirred and heated to near boiling to assist dissolution. The resulting green solution was then filtered and reduced in-vacuo. The solution was then cooled at -30oC yielding small green crystals. (0.44 g (87%)). m.p. 170oC(dec), C28H54Al2Cl12N2O12Pr2; calcd. Pr 10.27; found Pr 10.42% I.r absorption (Nujol): 2291w, 2253s, 1644w, 1353s, 1291s, 1248s, 1082s, 1034s, 966s, 925w, 878w, 837s, 802w cm-1. 27Al nmr: 104 ppm(AlCl4) † X-ray data for complex 1 was collected on a Nonius Kappa CCD, MoKà ¯Ã‚ Ã‚ ¡ radiation,à ¯Ã¢â€š ¬Ã‚  Ãƒ ¯Ã‚ Ã‚ ¬ = 0.71073 Ã…, T = 123(2)K. The structure was solved and refined using the programs SHELXS-97 17 and SHELXL-97 18 respectively. The program X-Seed 19 was used as an interface to the SHELX programs, and to prepare the figures. 1: [(Pr(Cl2)(C12H24O6))2][AlCl4]2.2(C2H3N): C28H54Al2Cl12N2O12Pr2, M = 1371.91, green prismatic, 0.40 à ¯Ã¢â‚¬Å¡Ã‚ ´ 0.40 à ¯Ã¢â‚¬Å¡Ã‚ ´ 0.30 mm, monoclinic, space group P21/n (No. 14), a = 12.377(3), b = 15.356(3), c = 14.387(3) Ã…,à ¯Ã¢â€š ¬Ã‚  Ãƒ ¯Ã‚ Ã‚ ¢ = 107.97(3) °, V = 2601.0(9) Ã…3, Z = 2, Dc = 1.752 g/cm3, F000 = 1360, Nonius Kappa CCD, MoKà ¯Ã‚ Ã‚ ¡ radiation,à ¯Ã¢â€š ¬Ã‚  Ãƒ ¯Ã‚ Ã‚ ¬ = 0.71073 Ã…, T = 123(2)K, 2à ¯Ã‚ Ã‚ ±max = 56.6 º, 20600 reflections collected, 6215 unique (Rint = 0.0864). Final GooF = 1.022, R1 = 0.0478, wR2 = 0.1052, R indices based on 4182 reflections with I >2sigma(I) (refinement on F2), 263 parameters, 0 restraints. Lp and absorption corrections applied,à ¯Ã¢â€š ¬Ã‚  Ãƒ ¯Ã‚ Ã‚ ­ = 2.551 mm-1. Fig. 2 The structure of the cation [{PrCl(à ¯Ã‚ Ã‚ ­-Cl)(18C6)}2]2+. Hydrogen atoms omitted for clarity. Thermal ellipsoids shown at 35%. Coordination environment of the atom Pr(1) with applicable bond lengths (Ã…) and angles(o). Symmetry transformations used to generate equivalent atoms: -x+1,-y+1,-z+1. Pr(1) O(1), O(2), O(3), O(4), O(5), O(6), Cl(1), Cl(2), Cl(2), 2.572(4), 2.579(4), 2.574(3), 2.590(4), 2.588(4), 2.587(6), 2.715(2), 2.839(2), 2.858(2). Cl(1)-Pr(1)-Cl(2), Cl(2), 144.30(4), 143.18(4), Cl(2) Pr Cl(2),72.52(4). Fig.1 Proposed cation structure observed prior to ether coordination and subsequent cleavage of Al– Cl bonds. 1Evans, W. J.; Rabe, G. W.; Ziller, J. W. Inorg. Chem 1994, 33, 3072-3078. 2Willey, G. R.; Aris, D. R.; Errington, W. Inorg. Chim. Acta 2001, 318, 97-102. 3Deacon, G. B.; Gortler, B.; Junk, P. C.; Lork, E.; Mews, R.; Petersen, J.; Zemva, B. J. Chem. Soc.-Dalton Trans 1998, 3887-3891. 4Hu, J.-Y.; Shen, Q.; Jin, Z.-S. Chinese.Sci.Bull 1990, 35, 1090. 5Shen, Q.; Hu, J.-Y.; Jin, Z.-S.; Sun, J. Zhongguo Xitu Xuebao (J. Chinese Rare Earth Society) 1990, 8, 359. 6Evans, W. J.; Johnston, M. A.; Greci, M. A.; Gummersheimer, T. S.; Ziller, J. W. Polyhedron 2003, 22, 119-126. 7Geary, W. J. J. Coord. Chem. 1971, 7, 81. 8Bunzli, J.-C. G.; Milicic-Tang, A. Inorg. Chim. Acta 1996, 252, 221-228. 9Cotton, F. A.; Schwotzer, W. Organometallics 1987, 6, 1275. 10Cotton, F. A.; Schwotzer, W. J. Am. Chem. Soc. 1986, 108, 4657. 11Rodgers, R. D.; Henry, R. F. Acta Cryst. Sect. C 1992, 48, 1099. 12Rodgers, R. D.; Rollins, A. N.; Etzenhouser, R. D.; Voss, E. J.; Bauer, C. B. Inorg. Chem 1993, 32, 3451. 13Crisci, G.; Meyer, G. Z. Anorg. Allg. Chem. 1994, 620, 1023-1027. 14Arndt, S.; Spaniol, T. P.; Okauda, J. Chem. Commun. 2002, 896. 15Deacon, G. B.; Feng, T.; Junk, P. C.; Skelton, B. W.; Sobolev, A. N.; White, A. H. Aust. J. Chem. 1998, 51, 75-89. 16Schwarzenbach, G.; Flaschka, H. A. Complexometric titrations; 2nd English ; ed.; Methuen: London,, 1969. 17Sheldrick, G. M. Acta Crystallogr., Sect. A 1990, 46, 467. 18Sheldrick, G. M. Shelx97; A program for crystal structure refinement; release 97-2 ed.: Germany, 1997. 19Barbour, L. J. Supramol. Chem 2001, 1, 189. 1

Comment Paper On Everything Th -- essays research papers

Everything That Rises Must Converge   Ã‚  Ã‚  Ã‚  Ã‚  In the story, “Everything That Rises Must Converge';; Flannery O’Conner uses a number of devices to make an organized plot. Causality, repetition, and structure all contribute in making the plot interesting.   Ã‚  Ã‚  Ã‚  Ã‚  The exposition consumes the beginning of the story. This is important because it gives the reader a better understanding of the characters, and sets tones for causality. Being introduced first is Julian’s mother. Her attitude and actions are best described on page 207. It states, “ She sat forward and looked up and down the bus. It was half filled. Everybody was white. ‘I see we have the bus to ourselves.'; This allows the reader to assume that Julian’s mother is prejudice, and was most likely raised in that time era. A good example O’Conner uses to explain Julian is found on page 208. It states, “Most miraculous of all, instead of being blinded by love for her as she was for him, he had cut himself emotionally free of her and could see her with complete objectivity. He was not dominated by his mother.'; It is safe to assume Julian is a depressed son, who is perturbed with his mother and her old ways of life.   Ã‚  Ã‚  Ã‚  Ã‚  Complications begin to arise after the reader has a good feel on who the characters are, which then leads to the climax of the story. Tension first arrives be...

American Politics in the Context of Obama’s Election and First 100 Days Essay

The election of Barack Hussein Obama as the 44th President of the United States is a watershed in the history of American politics. In a country were blacks were once prohibited from voting just because of the color of their skin, his ascent into the White House is indeed a milestone. Obama’s victory is often attributed to several factors, including changes in voting behavior and public opinion and constant media exposure. Popular support of his regime did not end with the election hype – a 2009 Associated Press-GfK poll revealed that about 48% of Americans were satisfied with the economic outcomes of the Obama presidency’s first 100 days (Philstar. com n. pag. ). The rise of the Obama regime had a tremendous impact on American politics. It brought about the prospect of women and minorities gaining a greater voice in political institutions. But Obama’s first 100 days in office told a different story. His first 100 days revealed that the substance of his regime remained largely the same as that of George W. Bush’s. This just goes to show that in the context of Obama’s election and first 100 days, American politics changed its style but retained its hegemonic and elitist nature. Winning the nomination proved to be a greater challenge for Obama than winning the general elections. Because of a national political machine attached to her and her husband, Hillary Clinton was initially chosen by the Democrat Party to become its presidential candidate (Ceaser, Busch and Pitney 15). Although Obama was young, charismatic, cerebral and self-assured, the Democrats were apprehensive about his lack of experience in the political scene (Ceaser, Busch and Pitney 16). This weakness would probably not sit well with the American electorate, who were desperate for a leader who could rectify the damaging mistakes of the Republican administration (Ceaser, Busch and Pitney 15). But shifts in the economic and demographic profile of American voters rendered Obama a more suitable presidential candidate than Clinton. As of 2004, about 56. 6% of American voters were below 30 years old (Dahl n. pag. ). Majority of these individuals grew up using the Internet as an indispensable tool for work, study and leisure. When the Clintons staged their last national campaign in 1996, the Internet was just a fledgling industry. Obama’s youth and tech savvy (he kept a Blackberry with him at all times), therefore, would make him more appealing to the aforementioned voter’s age group than Clinton (Ceaser, Busch and Pitney 106). Obama must have been aware of these advantages of his – his election campaign involved mainly the utilization of the Internet. By April 2007, he already had 1,543,000 â€Å"friends† in his account in the social-networking website MySpace. com. In sharp contrast, Clinton only had 41,500 people in her network (Dupuis and Boeckelman 123). In the spring of 2008, Obama had at least 1 million â€Å"friends† in Twitter, while Clinton only had 330,000. Although they had the same number of Facebook â€Å"friends† during this period, the website’s largest pro-Obama group had over 500,000 members, while the largest Facebook group that supported Clinton only had 30,000 members (Tapscott 252). Furthermore, Obama’s rhetoric reflected the American public’s disillusionment with traditional political ideologies. His slogan, â€Å"Change You Can Believe In,† appealed to voters because it did not bombard them with highfaluting dogmas. Rather, it showed them that â€Å"change† meant exploring for new solutions to problems. The American people did not have to make do with traditional solutions which Obama believed have already failed them in the past. For instance, he is constantly criticized for his relative youth and limited high-level government inexperience. Obama downplayed this attack by claiming that â€Å"Dick Cheney and Donald Rumsfeld have an awful lot of experience, and yet have engineered what I think is one of the biggest foreign policy failures in our recent history† (Dupuis and Boeckelman 123). Through this argument, he pointed out that adherence to convention is not always the best for the nation. There are instances when the government and the people must work together and come up with new solutions. In addition, Obama created a firm connection between himself and the people by letting them know that he also underwent their plights. In his campaign speeches, he often used his experience as the son of a working woman and as the husband of a working woman in order to show to the people that he knew how it felt to be in their shoes (Leanne 52). He knew how it was to be poor, marginalized and to work hard just to keep ends meet. Thus, his cynicism towards conventional ideologies – he and so many other Americans remained impoverished despite their application. Given such a populist and down-to-earth campaign strategy, it was no longer surprising if Obama won a landslide victory in the 2008 national elections. But his first 100 days in office revealed that his regime was essentially the same as that of George W. Bush’s. Obama’s first 100 days revealed the â€Å"right-wing character of his administration and the class interests that it serves† (Eley n. pag. ). If there was any difference at all, it was the approach – Bush assumed a warmonger-like stance to obtain the presidency, while Obama adopted a populist one. Obama continued the Bush administration’s militarist and aggressive foreign policy. Although he promised that he will all American troops out of Iraq, troop levels in Iraq remained virtually unchanged. Furthermore, Obama expanded the war in Afghanistan and even extended it to Pakistan. Worse, he proposed a defense budget worth $664 billion – believed to be the largest appropriation for military spending in American history (Eley n. pag. ). The prison camp at Guantanamo Bay remains open, despite Obama’s pledge to eventually close it down. As a result, its inmates are at risk of being shipped to US military prisons such as those in Iraq and Afghanistan, where they can be tortured and or killed in secret. Under the guise of â€Å"moving on,† he blocked all investigations and or criminal prosecution of parties that were responsible for the torture of detainees in US military prisons across the world. Obama’s government also intervened in the procedures of several court cases in order to deny habeas corpus to detainees in US military prisons in Afghanistan (Eley n. pag. ). While Obama was busy perpetuating Bush’s foreign policy, the American economy further deteriorated. Mounting layoffs took place, along with wage cuts, home foreclosures and depreciation of real estate value and retirement savings. These developments, in turn, resulted in escalating hunger and homelessness. But instead of creating concrete solutions to put an end to these calamities, the Obama administration used billions of dollars in public funds to bail financial institutions such as AIG, Lehman Brothers and Merrill Lynch out of bankruptcy. Worsening the situation was that these banks were discovered to have been doling out huge portions of the bailout money to their executives as â€Å"bonuses† (Eley n. pag. ). It is very ironic that Obama, a black man who experienced growing up poor and marginalized, would end up perpetuating the repressive and anti-poor policies of his predecessor. But what Obama did reflected the recourse that the US most probably resorted to in order to steer itself from the economic crisis – tighten its grip over the Third World. It is during the current economic crisis that the US needs unlimited access to the natural resources of the Third World more than ever before. Thus, the Obama administration’s promise of â€Å"change† was replaced with the de facto continuation of the Bush regime. Works Cited â€Å"AP Poll: After Obama’s 100 Days, US on Right Track. † 24 April 2009. Philstar. com. 4 May 2009 . Ceaser, James W. , Andrew E. Busch, and John J. Pitney. Epic Journey: The 2008 Elections and American Politics. New York: Rowman & Littlefield, 2009. Dahl, Melissa. â€Å"Youth Vote May have been Key in Obama’s Win. † 5 November 2008. MSNBC. 4 May 2009 . Dupuis, Martin, and Keith Boeckelman. Barack Obama: The New Face of American Politics. Santa Barbara: Greenwood Publishing Group, 2008. Eley, Tom. â€Å"Obama’s 100 Days. † 29 April 2009. GlobalResearch. ca. 4 May 2009 . Leanne, Shel. Say It Like Obama: The Power of Speaking with Purpose and Vision. New York: McGraw-Hill Professional, 2008. Tapscott, Don. Grown Up Digital: How the Net Generation is changing Your World. New York: McGraw-Hill Professional, 2008.

Rice Thailand Native Foods

Rice Thailand Native Foods Introduction Despite the fact that food is a commodity consumed by all people in the world, different countries and people are associated with a specific type of food which is native to them. The native food types of any country or ethnic group make the larger part of their cuisine as part of cultural representations.Advertising We will write a custom essay sample on Rice: Thailand Native Foods specifically for you for only $16.05 $11/page Learn More The specific food types therefore contribute to their culture and values in the society. However, there are regions that hold more to their cultures as compared to others. For example, most of the Asian nations still hold their cultural roots unlike their counterparts in Europe and America. This paper is therefore about the representative food(s) of an Asian nation known as Thailand. The Country’s food item Thailand is a country located in the south east of Asia. The common language spoken in Thailand is Thai hence making the Thai people. The country is endowed with many natural resources as well as agricultural products such as rice in which Thailand is the largest world exporter of rice (Cummings, 2000, p.211). Thus, rice is the staple food of the Thai people and especially the jasmine variety of rice which makes up the largest portion of the Thai cuisine. The Thai cuisine is known internationally because of the seasoning combination used. As a matter of fact, it is a blend of all the five key tastes namely spicy, sour, bitter, salty and sweet. The Thai cuisine is made up rice (Known as Khao in Thailand) that is served with other accompanying dishes made of sauces, salads and curries among others (Kahrs, 2000, p. 76). Its role, image and use Social occasions in Thailand are not complete without the Thai cuisine. As a matter of fact, food in Thailand can be a reason to hold celebrations, something that is very unusual in other nations. Apart from rice forming part of every meal in Thailand, it plays a great role in earning foreign income to the country. This is because, it exports rice to the world market and because of its high quality it has high demand in the market thus fetching much income (Schmidt, 2005, p.1). Rice has on the other hand created an image of Thailand globally. Thailand is among the first nations that people think of when you mention rice.Advertising Looking for essay on health medicine? Let's see if we can help you! Get your first paper with 15% OFF Learn More History of rice in Thailand For a long period of time rice has formed the heart of every meal in Thailand. Rice is said to have its origin in the Asian arc, from where it spread to other continents. However, the Thailand people have their own history with regard to the origin of rice. They claim that Lord Vishnu is the one who gave birth to rice thereafter the people were taught how to raise the rice by a God called Indra (Huke and Huke, 1990, p.1). It is be cause of this that the growth of rice in Thailand is considered as a holistic activity despite its economic and health benefits. Social and cultural roles of the Rice in Thailand Rice plays a big role in terms of social and cultural functions among the Thai people. It is the main food consumed during their social occasions and gatherings. As mentioned above, the practice of growing rice in Thailand is not only for health and economic benefits but it is also a cultural practice. It is the food that is used in shrines to give to the Thai gods. Studies done have also indicated that the spirit of rice is usually attached to the rice fields hence making rice a holistic commodity in Thailand. It is because of this that throwing away rice in Thailand is a taboo, which if gone against may lead to bad omen to the land. Religious uses The native food of Thailand has religious uses in that there is the ‘god of rice’ who gets very annoyed whenever rice is thrown away. The god of ri ce may cause bad luck or even phenomena such as famine whenever he is angry. It is therefore a taboo to throw away food and especially rice in Thailand. Because of this, most of the restaurants in Thailand have employed a deity who keeps watch as people eat to ensure that no food with rice is thrown away. In addition to this, since most people in Thai are Buddhists, they make food offerings in the temple which comprises of rice to feed the spirits. Conclusion From the above discussion it can be clearly seen that rice plays a great role among the people of Thailand as their staple or native food. This importance ranges from economic, food, social and cultural benefits. It has also been seen that rice is the forms the heart of the Thai cuisine (Schmidt, 2005, p.1).Advertising We will write a custom essay sample on Rice: Thailand Native Foods specifically for you for only $16.05 $11/page Learn More However, due to relations with their neighbouring countries, t he Thailand cuisine has had variations as compared to the traditional cuisine. This is because of the cultural influences from those countries. Nevertheless, the influences have not had much effect because the Thai cuisine is still internationally famous for its unique taste. Reference List Cummings, J. (2000). World Food Thailand. Victoria, Australia: Lonely Planet Publications Huke, R. and Huke, H. (1990). A Brief History of Rice. Web. Kahrs, K. (2003). Thai Cooking. Dallas: Hackberry Press. Schmidt, D. (2005). Thai Food and Culture. Retrieved from https://www.thespruceeats.com/thai-food-and-culture-3217393

resistance essays

resistance essays Investigating the Rate of Reaction Between Marble Chips Safety- must always wear safety glasses and we should be very careful not to drop any acid. Fair test- we must make sure that we use the same size, amount and roughly the same mass of chips, this is because we want to keep the chips roughly the same all the way through the experiment so that it will be a fair test and the results we be in relation to each other, otherwise the results will be completely different to what we will expect and it will ruin the experiment. We must also take our readings at the same intervals throughout the experiment i.e I will take a reading every fifteen seconds for all of my experiments. I predict that the more concentrated the acid the quicker the reaction will take place, because the more concentrated the acid is then it will make the chips react faster and more hydrogen will be given off in a quicker time. The smaller the stones are, the even quicker the reaction will happen, this is because the acid has a smaller surface area to act upon. Equipment- We will need a boiling tube, calcium carbonate chips, hydrochloric water, a stop watch, a gas syringe and a bung on the top of the boiling tube with a delivery tube connected to the gas syringe. I will also need a stand and a clamp to hold on to the syringe. When doing my exper...

Marketing Plan Phase II Essay Example | Topics and Well Written Essays - 500 words

Marketing Plan Phase II - Essay Example Pricing should not be seen in isolation of the other factors that have a bearing and often influence the decision itself. Predominantly price is part of a price-quality equation. The most important consideration in price decisions is its objectives. And objectives are in turn based on the strategy of product positioning. Commonly companies try to achieve any of five objectives through pricing: survival, maximize profit, maximize market share, skim the market or product-quality leadership. (Kotler, 2001, p. 458) "The business of businesses is business!" Friedman (as cited in Pohl, Eva, 1970, p.12). So understandably businesses exist to maximize profits. This then brings up for consideration the price-demand-profit relationship. This in other words is the demand for a product at different prices; which is the product's price sensitivity. "Price sensitivity is a measure of how important lower prices are to the customer" (Day, 1999, p. 114). In general products are less price sensitive if buyers are less aware of substitutes, when a one-on-one comparison between competing products is not possible and when a product is perceived to have quality and exclusivity. Bread is such routine fare. As such it is highly price sensitive. But Panera's customers don't see the company's products as just any bread. There is a definite value perception.

Unit 2 Seminar public health Essay Example | Topics and Well Written Essays - 250 words

Unit 2 Seminar public health - Essay Example The field entails bringing various resources, systems and techniques so as to maximize on the use of medical knowledge wealth, drug breakthroughs and technological advances available. Medical informatics services can be of help in various health settings, including hospital care, rehabilitation centers, primary care facilities and general practice (John, 2009). Health informants can be used to enhance efficiency and effectiveness of a given health facility. The commonest areas that require their services are the administrative, clinical and medical information (O’Carrol, 2010). For instance, there is a great emphasis for implementing a uniformed system of storing medical records electronically. Not only does it cut down health care cost, but also improves the general quality of care of clients. Furthermore, it also has an impact on billing, scheduling, sharing medical information and clinical research. Health communication and information provided by health informants have really been applied in the hospitals in a number of ways. Doctors generally take opportunity of the constantly expanding knowledge base which enables them to make decisions based on latest information. By health informants providing information on effectiveness of certain drugs, doctors eliminate some prescription mistakes they commit (O’Carrol,